| 贵金属纳米颗粒在玻碳电极上的层层组装 |
| |
| 引用本文： | 陈达,郑龙珍. 贵金属纳米颗粒在玻碳电极上的层层组装[J]. 中国化学, 2008, 26(2): 276-280. DOI: 10.1002/cjoc.200890054 |
| |
| 作者姓名： | 陈达 郑龙珍 |
| |
| 作者单位： | 中国科技大学化学系，合肥，安徽 230026 华东交通大学化学化工系，南昌，江西 330013 |
| |
| 摘 要： | 采用表面活性剂二辛酯琥珀酸磺酸钠(AOT, sodiumbis(2-ethylhexyl)sulfosuccinate)微乳法可以制备得到各种贵金属纳米颗粒(包括银、金、铂以及钯)，其性质利用紫外-可见吸收光谱、透射电镜、X-射线衍射、傅立叶变换红外光谱以及Zeta电位分析进行了表征。通过层层自组装方法，将带有负电荷的Pt纳米颗粒和聚阳离子(聚烯丙基氯化铵, PAH)自组装到玻碳电极上，并研究了该修饰电极对甲醇的电催化氧化性质。
|
| 关 键 词： | Pt纳米颗粒 Zeta电位 负电性质 自组装 电催化反应 |
| 收稿时间： | 2005-12-12 |
| 修稿时间： | 2007-06-18 |
Layer‐by‐layer Assembly of Noble Metal Nanoparticles on Glassy Carbon Electrode |
| |
| Da CHEN,Long‐Zhen ZHENG. Layer‐by‐layer Assembly of Noble Metal Nanoparticles on Glassy Carbon Electrode[J]. Chinese Journal of Chemistry, 2008, 26(2): 276-280. DOI: 10.1002/cjoc.200890054 |
| |
| Authors: | Da CHEN Long‐Zhen ZHENG |
| |
| Affiliation: | Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China |
| |
| Abstract: | Silver, gold, platinum and palladium nanoparticles were initially prepared in the AOT [sodium bis(2‐ethylhexyl)‐ sulfosuccinate] micelle and characterized by ultraviolet‐visible spectroscopy, transmission electron macroscopy, X‐ray diffraction, Fourier transform‐infrared spectroscopy, and zeta potential analysis. The negatively charged Pt nanoparticles were self‐assembled on a glassy carbon electrode by a layer‐by‐layer method and the modified electrode electrocatalytic reactivity toward methanol oxidation was studied. |
| |
| Keywords: | Pt nanoparticle zeta potential negatively charged self‐assembly electrocatalytic reactivity |
|
| 点击此处可从《中国化学》浏览原始摘要信息 |
|
点击此处可从《中国化学》下载全文 |
