Rhodium and iridium complexes of a new ferrocene-derived chelating bis(NHC) ligand |
| |
| Authors: | Dmitriy M Panov Pavel V Petrovskii Mariam G Ezernitskaya Alexander F Smol'yakov Fedor M Dolgushin Avthandil A Koridze |
| |
| Institution: | A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, 119991 Moscow, Russian Federation. |
| |
| Abstract: | Rhodium and iridium complexes of a new ferrocene-derived bis(N-heterocyclic carbene) ligand, M(cod){1,2-(MeNCHCHNCCH(2))(2)C(5)H(3)}Fe(C(5)H(5))]BF(4) (M = Rh, 8a; M = Ir, 8b; cod = 1,5-cyclooctadiene), were synthesized from the corresponding bis(imidazolium) salt 6. The molecular structure of 8a was determined by single-crystal X-ray diffraction. Complexes 8a and 8b smoothly react with CO with displacement of the chelating cod ligand to give the corresponding dicarbonyl derivatives 9a and 9b. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
