|
|||||
|
|
| 亲水性有机硅杂化防雾涂料的制备及性能 | |
| 引用本文： | 沙鹏宇,刘岩,谢雷,崔占臣. 亲水性有机硅杂化防雾涂料的制备及性能[J]. 高等学校化学学报, 2007, 28(11): 2205-2209 |
| 作者姓名： | 沙鹏宇 刘岩 谢雷 崔占臣 |
| 作者单位： | 吉林大学化学学院,超分子结构与材料教育部重点实验室,长春,130023;吉林大学化学学院,超分子结构与材料教育部重点实验室,长春,130023;吉林大学化学学院,超分子结构与材料教育部重点实验室,长春,130023;吉林大学化学学院,超分子结构与材料教育部重点实验室,长春,130023 |
| 基金项目： | 国家重点基础研究发展计划(973计划) , 教育部长江学者和创新团队发展计划 , 国家高技术研究发展计划(863计划) |
| 摘 要： | 采用Sol-Gel技术制备了二乙醇胺/有机硅杂化涂料, 并用FTIR、UV-Vis、AFM、TGA及接触角等测试技术对涂料及其涂层进行了分析表征. 结果表明, 该杂化涂料具有良好的成膜性. 由于膜层中存在大量的亲水性羟基基团, 使膜层具有良好的亲水性能和防雾效果. 固化后的聚合物膜层中无机相形成了三维交联网络, 赋予了膜层优异的耐磨性和热稳定性. |
| 关 键 词： | 亲水性 溶胶凝胶法 防雾涂料 杂化材料 |
| 文章编号： | 0251-0790（2007）11-2205-05 |
| 收稿时间： | 2007-04-28 |
| 修稿时间： | 2007-04-28 |
Preparation and Properties of Hydrophilic DEA/Organosilane Hybrid Antifogging Coating |
|
| SHA Peng-Yu,LIU Yan,XIE Lei,CUI Zhan-Chen. Preparation and Properties of Hydrophilic DEA/Organosilane Hybrid Antifogging Coating[J]. Chemical Research In Chinese Universities, 2007, 28(11): 2205-2209 | |
| Authors: | SHA Peng-Yu LIU Yan XIE Lei CUI Zhan-Chen |
| Affiliation: | Key Laboratory of Supramolecular Structure and Materials of Ministry of Education, College of Chemistry Jilin University, Changchun 130023, China |
| Abstract: | The TEOS-derived silica was modified with epoxy by copolymerization of TEOS with GPTMS. The epoxy sites have become anchors for cross-linking the nanoparticles of the skeletal backbone of the silica hybrids by attachment of DEA. The synthesis material was determined by FTIR, TGA and AFM . The hybrids have an excellent film-forming capability and possess a high thermstability. After addition of DEA, the inorganic-organic hybrid system containing abundant —OH group has a wettable surface and long antifogging time. The contact angles of the hybrid film for water were less than 31° and the coating meet the requirements for transparence. The existing silica gel network improved the scratch property. So the coating have an exce-llent mechanical property. |
| Keywords: | Hydrophilicity Sol-gel method Antifogging coating Hybrid material |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 | |
| 点击此处可从《高等学校化学学报》下载全文 | |