Mass-spectrometric determination of the 4-center configuration in trans-linked 1,4-dialkyldecahydroquinolol-4′s期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Mass-spectrometric determination of the 4-center configuration in trans-linked 1,4-dialkyldecahydroquinolol-4′s

Authors:	Zaikin V G Smetanin V I Vul'fson N S Akhrem A A Ukhova L I Kukso G P

Institution:	(1) A. V. Topchiev Institute of Petrochemical Syntheses, Academy of Sciences of the USSR, Moscow;(2) M. M. Shemyakin Institute of Bioorganic Chemistry, Academy of Sciences of the USSR, Moscow;(3) Institute of Bioorganic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk

Abstract:	Conclusions By studying molecular ion stabilities and values of the $I_{M - C_2 H_5 ]^ + } /I_{M]^ + }$ ratio (the M-C₂H₅]⁺ results from 4-C₂H₅ group elimination), we have been led to 4-center configurations for the trans-linked 1-alkyl-4-ethyl(ethynyl)decahydroquinolol-4s (Alk=CH₃, C₂H₅, n-and i-C₃H₇).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1524–1529, July, 1976.

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