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A three-parameter model describing the behaviour of a viscoelastic liquid in a tangential annular flow
Authors:P J Hamersma  J Ellenberger  J M H Fortuin
Institution:(1) Laboratory of Chemical Engineering, University of Amsterdam, Plantage Muidergracht 30, NL-1018 TV Amsterdam, The Netherlands
Abstract:A three-parameter model describing the shear rate-shear stress relation of viscoelastic liquids and in which each parameter has a physical significance, is applied to a tangential annular flow in order to calculate the velocity profile and the shear rate distribution. Experiments were carried out with a 5000 wppm aqueous solution of polyacrylamide and different types of rheometers. In a shear-rate range of seven decades (5 sdot 10–3 s–1 < 
$$\dot \gamma$$
< 1.2 sdot 105 s–1) a good agreement is obtained between apparent viscosities calculated with our model and those measured with three different types of rheometers, i.e. Couette rheometers, a cone-and-plate rheogoniometer and a capillary tube rheometer. a physical quantity defined by:a = {1 – (eegr infin/eegr 0)}/tau 0 (Pa–1) - C constant of integration (1) - r distancer from the center (m) - r 1,r 2 radius of the inner and outer cylinder (m) - v rtheta local tangential velocity at a distancer from the center (v rtheta =ohgr rtheta r) (m s–1) - v 2 local tangential velocity at a distancer 2 from the center (m s–1) - 
$$\dot \gamma$$
shear rate (s–1) - 
$$\dot \gamma _{r\theta }$$
local shear rate 
$$\left\{ {r\frac{d}{{dr}}\left( {\frac{{\upsilon _{r\theta } }}{r}} \right)} \right\}$$
(s–1) - 
$$\dot \gamma$$
1 wall shear rate at the inner cylinder (s–1) - eegr dynamic viscosity (Pa s) - eegr a apparent viscosity (eegra = tau/ 
$$\dot \gamma$$
) (Pa s) - eegr a1 apparent viscosity at the inner cylinder (Pa s) - eegr 0 zero-shear viscosity (Pa s) - eegr infin infinite-shear viscosity (Pa s) - tau shear stress (Pa) - tau rtheta local shear stress at a distancer from the center (Pa) - tau 0 yield stress (Pa) - tau 1,tau 2 wall shear-stress at the inner and outer cylinder (Pa) - ohgr rtheta local angular velocity (s–1) - ohgr 2 angular velocity of the outer cylinder (s–1)
Keywords:Couette flow  polymer solution  shear stress  shear rate  three-parameter model
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