Meridional bicyclometalation with iron: a novel way of forming dianionic [C,N,C]-ligands |
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| Authors: | Klein Hans-Friedrich Camadanli Sebnem Beck Robert Flörke Ulrich |
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| Institution: | Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universit?t Darmstadt, Petersenstrasse 18, D-64287, Darmstadt, Germany. HFKLEIN@ac.chemie.tu-darmstadt.de |
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| Abstract: | Bicyclometalation of aromatic substrates containing imine anchoring groups is achieved with a dimethyliron complex at -70 degrees C; azadiene systems undergo a regiospecific activation of 1,4-CH/N interchanged C-H bonds which may be aromatic or vinylic. |
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