The effect of Pd addition to Fe as catalysts on growth of carbon nanotubes by TCVD method |
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| Authors: | SZ Mortazavi A Iraji zad |
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| Institution: | a Department of Physics, Sharif University of Technology, P.O. Box 1155-9161, Tehran, Iran
b Institute for Nanoscience and Nanotechnology (INST), Sharif University of Technology, P.O. Box, 11155-8639, Tehran, Iran |
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| Abstract: | The effects of Pd addition to Fe (Pd/Fe = 0, 2.5/7.5, 5/5, 7.5/2.5 and 1) and growth temperatures (920 and 970 °C) on density, diameter and growth mode of carbon nanotubes (CNTs) have been studied. SEM observations and TG analyses confirmed that the CNT yields depend on Pd/Fe ratios as (7.5/2.5) > (5/5) > Pd > (2.5/7.5) > Fe at both growth temperatures. TEM data showed that addition of Pd results in tip growth mode. From Raman spectroscopy data, the order of samples’ structural quality (IG/ID ratio) are Fe > Pd/Fe (2.5/7.5) > (5/5) > (7.5/2.5) > Pd and the IG/ID ratios increase by decreasing the growth temperature. Films with higher concentration of Fe (Pd/Fe = 0, 2.5/7.5) contain some single-walled carbon nanotubes. |
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| Keywords: | Carbon nanotube Thermal chemical vapor deposition Pd/Fe catalyst |
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