|
|||||
|
|
Cyclization of Pyrene Oligomers: Cyclohexa‐1,3‐pyrenylene |
|
| Authors: | Dominik Lorbach Dr Ashok Keerthi Dr Teresa Marina Figueira‐Duarte Prof?Dr Martin Baumgarten Dr Manfred Wagner Prof?Dr Klaus Müllen |
| Institution: | Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany) |
| Abstract: | First synthesis of the macrocycle cyclohexa(1,3‐pyrenylene) is achieved in six steps starting with pyrene, leading to a non‐aggregating highly twisted blue‐light‐emitting material. The cyclodehydrogenation of the macrocycle offers a promising synthesis route to holey‐nanographene. |
| Keywords: | atropisomerism cyclodehydrogenation holey‐nanographene macrocycles pyrene |