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The [B3(NN)3]+ and [B3(CO)3]+ Complexes Featuring the Smallest π‐Aromatic Species B3+ |
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| Authors: | Jiaye Jin Prof. Guanjun Wang Prof. Mingfei Zhou Dr. Diego M. Andrada Dr. Markus Hermann Prof. Gernot Frenking |
| Affiliation: | 1. Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai, China;2. Fachbereich Chemie, Philipps-Universit?t Marburg, Marburg, Germany |
| Abstract: | We report the spectroscopic identification of the [B3(NN)3]+ and [B3(CO)3]+ complexes, which feature the smallest π‐aromatic system B3+. A quantum chemical bonding analysis shows that the adducts are mainly stabilized by L→[B3L2]+ σ‐donation. |
| Keywords: | aromaticity bonding analysis coordination chemistry photodissociation physical chemistry |