Lattice dynamical calculation of the second Grüneisen constant of CsBr

The second order Grüneisen constant constitutes an additional measure of the anharmonicity in a solid (the Grüneisen constant itself being the first measure). This quantity and the corresponding second mode-Grüneisen parameters are calculated for CsBr using a modified rigid ion model of lattice dynamics. The model parameters are deduced from the three elastic constants and the long wavelength optical mode frequencies. Using the first and second order pressure dependences of these physical observables, the individual second mode-Grüneisen parameters are obtained as a function of wave vector. The temperature variation of the second Grüneisen constant is then deduced in a quasi-harmonic approximation. The second Grüneisen constant is also calculated from available thermodynamic data and is in reasonable agreement with the present theoretical prediction.