Stereoselective RhI-catalyzed tandem conjugate addition of boronic acids-Michael cyclization |
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| Authors: | Navarro Cristina Csákÿ Aurelio G |
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| Affiliation: | Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040-Madrid, Spain. |
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| Abstract: | ![]()
The first examples of the stereoselective sequence RhI-catalyzed tandem conjugate addition of boronic acids to enones-Michael cyclization, is reported. The reaction is carried out in dioxane-H2O at rt, and 1,2,3-trisubstituted indans are obtained in a highly regio- and stereoselective fashion. |
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