| Synthesis of New Chiral Bis(BINOL) Substituted 2,2'-Bipyridine Ligands |
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| 作者姓名： | BAI Xiao-Li
GAO Lian-Xun |
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| 作者单位： | BAI,Xiao-Li（State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022）
GAO,Lian-Xun（State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022） |
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| 摘 要： | Chiral 2,2'-bipyridines have been reported to be highly efficient catalysts and useful building blocks of supramolecular.1,2] Chirality of bipyridines was introduced by chiral substituents. Because 1,1'-binaphthyl (BINOL) and its derivatives belong to the most important components of asymmetric catalysts, we would like to synthesize 5,5'-and 6,6'-positions substituted chiral bipyridine-type ligands, the chiral moieties of ligands originate from enationpure 1, 1'-binapthyl units.
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Synthesis of New Chiral Bis(BINOL) Substituted 2,2'-Bipyridine Ligands |
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| BAI,Xiao-Li,GAO,Lian-Xun.Synthesis of New Chiral Bis(BINOL) Substituted 2,2''''-Bipyridine Ligands[J].Chinese Journal of Organic Chemistry,2004,24(Z1):34. |
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| Authors: | BAI Xiao-Li GAO Lian-Xun |
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| Abstract: | Chiral 2,2'-bipyridines have been reported to be highly efficient catalysts and useful building blocks of supramolecular.1,2] Chirality of bipyridines was introduced by chiral substituents. Because 1,1'-binaphthyl (BINOL) and its derivatives belong to the most important components of asymmetric catalysts, we would like to synthesize 5,5'-and 6,6'-positions substituted chiral bipyridine-type ligands, the chiral moieties of ligands originate from enationpure 1, 1'-binapthyl units. |
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