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Investigation into the ROMP copolymerization of peptide‐ and PEG‐functionalized norbornene derivatives
Authors:Alison L. Parry
Affiliation:Functional Materials Group, Chemical Laboratory, School of Physical Sciences, University of Kent at Canterbury, Canterbury, Kent CT2 7NR, United Kingdom
Abstract:The ring‐opening metathesis polymerizations (ROMP), using RuCl2 (PCy3)2CHPh, of a series of peptide‐functionalized norbornene derivatives have been investigated. Incorporation of a PEG‐monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3178–3190, 2007
Keywords:copolymerization  peptides  poly(vinyl ethers)  ROMP
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