Synthesis and structural characterization of a molecular plutonium(IV) compound constructed from dimeric building blocks |
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Authors: | Runde Wolfgang Brodnax Lia F Goff George S Peper Shane M Taw Felicia L Scott Brian L |
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Affiliation: | Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA. runde@lanl.gov |
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Abstract: | Single crystals of Na(8)Pu(2)(O(2))(2)(CO(3))(6) x 12H(2)O, exhibiting bridging mu(2),eta(2)-O(2) ligands in unprecedented Pu(IV) dimeric units, were obtained at ambient temperature from an aqueous Pu(IV) peroxide carbonate solution. |
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