Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin |
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Authors: | Richeter Sébastien Hadj-Aïssa Aurélie Taffin Céline van der Lee Arie Leclercq Dominique |
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Affiliation: | Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France. Sebastien.Richeter@univ-montp2.fr |
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Abstract: | ![]() The functionalisation of two neighboring beta-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented. |
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