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Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin
Authors:Richeter Sébastien  Hadj-Aïssa Aurélie  Taffin Céline  van der Lee Arie  Leclercq Dominique
Affiliation:Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France. Sebastien.Richeter@univ-montp2.fr
Abstract:
The functionalisation of two neighboring beta-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented.
Keywords:
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