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Bismuth-content-dependent polarized Raman spectrum of InPBi alloy
Institution:1.State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China;2.State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China
Abstract:We systematically investigate the optical properties of the InP1-xBix ternary alloys with 0≤ x≤ 2.46%, by using high resolution polarized Raman scattering measurement. Both InP-like and InBi-like optical vibration modes (LO) are identified in all the samples, suggesting that most of the Bi-atoms are incorporated into the lattice sites to substitute P-atoms. And the intensity of the InBi-like Raman mode is positively proportional to the Bi-content. Linear red-shift of the InP-like longitudinal optical vibration mode is observed to be 1.1 cm-1/Bi%, while that of the InP-like optical vibration overtone (2LO) is nearly doubled. In addition, through comparing the Z(XX)Z and Z(XY)Z Raman spectra, longitudinal-optical-plasmon-coupled (LOPC) modes are identified in all the samples, and their intensities are found to be proportional to the electron concentrations.
Keywords:InPBi  Raman spectra  red-shift  LOPC modes  
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