| MnFe2O4晶体的基态能级和零场分裂参量 |
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| 引用本文： | 殷春浩,张国营,尹钊. MnFe2O4晶体的基态能级和零场分裂参量[J]. 原子与分子物理学报, 2003, 20(2): 243-246 |
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| 作者姓名： | 殷春浩 张国营 尹钊 |
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| 作者单位： | 1. 中国矿业大学理学院,中国江苏,徐州,221008
2. 徐州师范大学物理系,中国江苏,徐州,221009 |
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| 基金项目： | 中国矿业大学理学院人才工程教授类项目资助(批准号:CL-001.6) |
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| 摘 要： | 由不可约张量理论构成一个3d4/3d6离子三角(C3V)对称的晶体场和自旋-轨道相互作用哈密顿矩阵,由这个晶体场和自旋-轨道相互作用哈密顿矩阵被完全对角化后能够求出MnFe2O4晶体中的Fe2+离子的电子顺磁共振零场分裂参量D和F-a,计算了低自旋态(3L态)对电子顺磁共振零场分裂参量(D,F-a)的贡献.结果显示低自旋3L态对电子顺磁共振的零场分裂参量的贡献是较强的.理论计算的结果与实验值是相符的.
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| 关 键 词： | 哈密顿量 晶体场 低自旋态 高自旋态 零场分裂 自旋-轨道相互作用 |
Ground states energy levels and zero-field splitting parameters in MnFe2O4 crystal |
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| YIN Chun hao ,ZHANG Guo ging ,YIN Zhao. Ground states energy levels and zero-field splitting parameters in MnFe2O4 crystal[J]. Journal of Atomic and Molecular Physics, 2003, 20(2): 243-246 |
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| Authors: | YIN Chun hao ZHANG Guo ging YIN Zhao |
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| Affiliation: | YIN Chun hao 1,ZHANG Guo ging 1,YIN Zhao 2 |
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| Abstract: | The crystal field and spin orbit interaction complete diagonalizing Hamiltonian matrix of 3d 4/3d 6 ions have been composed by irreducible representation method.The zero field spltting parameters D and F-a of Fe 2+ ions in MnFe 2O 4 crystal are presented by the crystal field and spin orbit interaction complete diagonalizing Hamiltonian matrix with theory of electron paramagnetic resonance. At the same time, the contribution of low spin states to zero field splitting parameters have been studied. The results show that contribution of low spin states to zero field splitting parameters is important and strong. The calculated results are in good agreement with the experimental data. |
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| Keywords: | Hamiltonian parameter Crystal field Low spin state High spin state Zero field splitting Spin orbit interaction |
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