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FTIR光谱高温气体浓度反演方法及残差结构分析
引用本文:Cheng SY,Zhang TS,Gao MG,Liu ZM,Tong JJ,Jin L. FTIR光谱高温气体浓度反演方法及残差结构分析[J]. 光谱学与光谱分析, 2011, 31(1): 82-85. DOI: 10.3964/j.issn.1000-0593(2011)01-0082-04
作者姓名:Cheng SY  Zhang TS  Gao MG  Liu ZM  Tong JJ  Jin L
作者单位:中国科学院环境光学与技术重点实验室,中国科学院安徽光学精密机械研究所环境光学中心,安徽合肥,230031
基金项目:国家自然科学基金项目(60708011)资助
摘    要:
从理论和实验两方面分析了光谱线线宽随温度的变化规律.将HITRAN数据库中常温下的线强参数修正到了测量温度,进而得到合成校准光谱.将合成校准光谱和实验测得的光谱进行非线性最小二乘拟合,得到了不同温度下标准气体CO浓度.这种反演算法的浓度误差在常温下不超过5%,具有很高的精度,但随温度升高浓度误差逐渐增大.从残差光谱曲线...

关 键 词:傅里叶变换红外光谱  高温气体  浓度反演  残差

Concentration inversion of high temperature air from FTIR spectra and analyzing residual error structure
Cheng Si-Yang,Zhang Tian-Shu,Gao Min-Guang,Liu Zhi-Ming,Tong Jing-Jing,Jin Ling. Concentration inversion of high temperature air from FTIR spectra and analyzing residual error structure[J]. Spectroscopy and Spectral Analysis, 2011, 31(1): 82-85. DOI: 10.3964/j.issn.1000-0593(2011)01-0082-04
Authors:Cheng Si-Yang  Zhang Tian-Shu  Gao Min-Guang  Liu Zhi-Ming  Tong Jing-Jing  Jin Ling
Affiliation:CHENG Si-yang,ZHANG Tian-shu,GAO Min-guang,LIU Zhi-ming,TONG Jing-jing,JIN Ling Key Lab of Environment Optics & Technology,and Anhui Institute of Optics and Fine Mechanics,Chinese Academy of Sciences,Hefei 230031,China
Abstract:
The spectral line widths of theory and experiment are analyzed with different temperatures;the line strengths under room temperature in HITRAN database are corrected to measured temperature,and then synthetic spectra are calculated.With the nonlinear least squares fit between measured spectra and calibration spectra,standard gas concentrations of CO at different temperatures are obtained.The inversion concentration error of this algorithm at room temperature is less than 5% with high precision.But with the ...
Keywords:FTIR  High temperature air  Concentration inversion  Residual error  
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