| 脲基苯乙炔4-′(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物的合成 |
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| 引用本文： | 潘敦,吴骊珠,武小玲,张丽萍,佟振合.脲基苯乙炔4-′(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物的合成[J].影像科学与光化学,2006,24(2). |
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| 作者姓名： | 潘敦 吴骊珠 武小玲 张丽萍 佟振合 |
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| 基金项目： | 中国科学院资助项目;科技部科研项目;中国科学院知识创新工程项目 |
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| 摘 要： | 本文通过异氰酸酰化反应合成了含有脲基的苯乙炔新型配体及以它作为辅助配体的4′-(对甲基苯基)-6-苯基-2,2′-二联吡啶铂(II)络合物,初步研究了铂(II)络合物的光物理性质,发现由于脲基的存在,当浓度大于3.32×10-5mol/L时铂(II)络合物能够发生分子间簇集.
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| 关 键 词： | 多吡啶铂(II)络合物 脲基苯乙炔辅助配体 簇集 |
Synthesis and Photophysical Studies of Platinum(Ⅱ) Polypyridine Complexes by Ancillary Urea Acetylide Ligand |
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| PAN Dun,WU Li-zhu,WU Xiao-ling,ZHANG Li-ping,TUNG Chen-ho.Synthesis and Photophysical Studies of Platinum(Ⅱ) Polypyridine Complexes by Ancillary Urea Acetylide Ligand[J].Imaging Science and Photochemistry,2006,24(2). |
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| Authors: | PAN Dun WU Li-zhu WU Xiao-ling ZHANG Li-ping TUNG Chen-ho |
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| Institution: | PAN Dun,WU Li-zhu,WU Xiao-ling,ZHANG Li-ping,TUNG Chen-ho(TONG Zhen-he) |
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| Abstract: | 4′-tolyl-cyclometalated platinum(II) complex with urea acetylide as an ancillary ligand(P2) has been synthesized,and its photophysical properties have been investigated.It is noted that P2 tends to aggregate under relative low concentration in nonpolar solvent. |
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| Keywords: | platinum(II) polypyridine complexes ancillary urea acetylide ligand aggregation |
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