| Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality |
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| 引用本文： | 朱士正 章正祥 金桂芳 DesMarteau,DarrylD.. Synthesis and Characterization of a Novel Perfluorinated Ionomer Polymer Containing Sulfonimide Functionality[J]. 中国化学, 2003, 21(7): 921-925. DOI: 10.1002/cjoc.20030210740 |
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| 作者姓名： | 朱士正 章正祥 金桂芳 DesMarteau DarrylD. |
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| 作者单位： | [1]ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China [2]DepartmentofChemistry,H.L.HunterChemistryLaboratoryClemsonUniversity,Clemson,SC29634-1905 |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.20032010,20072049). |
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| 摘 要： | The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetrafluoroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied.
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| 关 键 词： | 合成 表征 全氟离子交联聚合物 磺胺 官能度 全氟乙烯基醚 四氟乙烯 共聚物 单体 物理性质 化学性质 |
Synthesis and Characterization of a Novel Perfluorinated lonomer Polymer Containing Sulfonimide Functionality |
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| ZHU,Shi-Zheng ZHANG,Yun-Xiang JIN,Gui-FangDesMarteau,Darryl D. Synthesis and Characterization of a Novel Perfluorinated lonomer Polymer Containing Sulfonimide Functionality[J]. Chinese Journal of Chemistry, 2003, 21(7): 921-925. DOI: 10.1002/cjoc.20030210740 |
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| Authors: | ZHU Shi-Zheng ZHANG Yun-Xiang JIN Gui-FangDesMarteau Darryl D |
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| Affiliation: | ZHU,Shi-Zheng ZHANG,Yun-Xiang JIN,Gui-FangDesMarteau,Darryl D. Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China Department of Chemistry,H. L. Hunter Chemistry Laboratory Clemson University,Clemson,SC 29634-1905 |
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| Abstract: | The novel perfluorinated vinyl ether containing sulfonimide functionality CF2 = CFORfSO2NHSO2CF3 was synthesized by multiple reaction steps. It could be copolymerized with tetraflu-oroethylene by radox initiator to give a novel perfluorinated ionomer polymer. Its physical and chemical properties were studied. |
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| Keywords: | perfluorinated vinyl ether sulfonimide copolymer-ization ionomer resin |
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