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Liquid membranes for gas/vapor separations
Authors:FF Krull  C Fritzmann  T Melin
Institution:Aachener Verfahrenstechnik, Chemical Reaction Engineering, RWTH Aachen University, Turmstr. 46, 52056 Aachen, Germany
Abstract:A review on developments of liquid membranes (LMs) in the field of gas and vapor separation of the last 16 years is presented. Liquid membrane configurations employing supports, i.e. immobilized, supported and contained liquid membranes are focussed and detailed information on the respective materials, i.e. supports (supplier, type, thickness, pore width, porosity, tortuosity), liquids and carriers, are presented together with their specific separation tasks. Performance of different LMs in terms of permeability and selectivity as well as stability (duration of testing, applied differential pressures) are compared and discussed. Finally, different preparation methods of LMs are illustrated.
Keywords:BEHA  bis(2-ethylhexyl)amine  CA  carbonic anhydrase  CAN  cellulose acetate-nitrate  CLM  contained liquid membrane  CUN  cuprophan  DAE  diaminoethane  DBC  dibenzo-18-crown-6  DEA  diethanolamine  DETA  diethylenetriamine  DEYA  diethylamine  DGA  diglycolamine  DIPA  diisopropanolamine  EDA  ethylenediamine  ELM  emulsion liquid membrane  FS  flat sheet  HF  hollow fiber  IL  ionic liquid  ILM  immobilized liquid membrane  LiAlO2  lithium aluminate  LM  liquid membrane  MEA  monoethanolamine  MS  molten salt  NA  not available  PAA  porous anodic alumina  PAMAM  polyamidoamine dendrimer  PAN  polyacrylonitrile  PEG  polyethyleneglycol  PES  polyethersulfone  PP  polypropylene  PS  polysulfone  PTMSP  polytrimethylsilylpropyne  PVDF  polyvinylidinedifluoride  SLM  supported liquid membrane  TEG  triethyleneglycol
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