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Inclusion complexes of trivalent lutetium cations with an acidic derivative of per(3,6-anhydro)-alpha-cyclodextrin
Authors:Bonnet Célia  Gadelle Andrée  Pécaut Jacques  Fries Pascal H  Delangle Pascale
Institution:Laboratoire de Reconnaissance Ionique, SCIB, CEA/DSM/DRFMC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France.
Abstract:The cyclodextrin derivative (hexakis (2-O-carboxymethyl-3,6-anhydro)-alpha-cyclodextrin) forms mono- and bimetallic complexes with lutetium(III) in aqueous solution; the X-ray structure of the binuclear complex Lu2(ACX)(H2O)2] is the first example of a lanthanide-cyclodextrin inclusion complex.
Keywords:
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