Inclusion complexes of trivalent lutetium cations with an acidic derivative of per(3,6-anhydro)-alpha-cyclodextrin |
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Authors: | Bonnet Célia Gadelle Andrée Pécaut Jacques Fries Pascal H Delangle Pascale |
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Institution: | Laboratoire de Reconnaissance Ionique, SCIB, CEA/DSM/DRFMC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France. |
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Abstract: | The cyclodextrin derivative (hexakis (2-O-carboxymethyl-3,6-anhydro)-alpha-cyclodextrin) forms mono- and bimetallic complexes with lutetium(III) in aqueous solution; the X-ray structure of the binuclear complex Lu2(ACX)(H2O)2] is the first example of a lanthanide-cyclodextrin inclusion complex. |
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