Iron porphyrins anchored to a thermosensitive polymeric core-shell nanosphere as a thermotropic catalyst |
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Authors: | Choi Bo Gyu Song Rita Nam Wonwoo Jeong Byeongmoon |
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Institution: | Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea. |
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Abstract: | A thermosensitive nanocatalyst was prepared in the reaction of water-soluble iron(III) porphyrins and thermosensitive polymeric nanospheres with a core-shell structure; its catalytic activity in cyclohexene oxidation by iodosylbenzene was dependent markedly on reaction temperatures in aqueous solution. |
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