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Iron porphyrins anchored to a thermosensitive polymeric core-shell nanosphere as a thermotropic catalyst
Authors:Choi Bo Gyu  Song Rita  Nam Wonwoo  Jeong Byeongmoon
Institution:Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.
Abstract:A thermosensitive nanocatalyst was prepared in the reaction of water-soluble iron(III) porphyrins and thermosensitive polymeric nanospheres with a core-shell structure; its catalytic activity in cyclohexene oxidation by iodosylbenzene was dependent markedly on reaction temperatures in aqueous solution.
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