| 盐酸三甲胺三氧化铬／硅胶载体试剂的制备及其对苯偶姻体系的氧化 |
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| 引用本文： | 张贵生 石启增. 盐酸三甲胺三氧化铬／硅胶载体试剂的制备及其对苯偶姻体系的氧化[J]. 合成化学, 1997, 5(2): 218-220 |
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| 作者姓名： | 张贵生 石启增 |
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| 作者单位： | 河南师范大学化学系 |
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| 基金项目： | 国家自然科学基金,河南省基础研究基金 |
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| 摘 要： | 报道了盐酸三甲胺三氧化锆／硅胶载体试剂的制备方法及其对苯偶姻的氧化反应。该试剂制备简单，用于地苯偶姻的氧化，高收率地得到相应的苯偶酰在化合物，并且反应条件温和，产物易分离。
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| 关 键 词： | 盐酸三甲胺 三氧化铬 硅胶 苯偶姻 苯偶酰 氧化 |
Preparation of Trimethylammonium Chlorochromate Adsorbed on Silica Gel and Its Use in Oxidation of Benzoins |
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| Zhang,Gui Sheng Shi,Qi Zeng Chen,Mi Feng Cai,Kun. Preparation of Trimethylammonium Chlorochromate Adsorbed on Silica Gel and Its Use in Oxidation of Benzoins[J]. Chinese Journal of Synthetic Chemistry, 1997, 5(2): 218-220 |
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| Authors: | Zhang Gui Sheng Shi Qi Zeng Chen Mi Feng Cai Kun |
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| Abstract: | Trimethylammonium chlorochromate adsorbed on silica gel was described as a convenient reagent for oxidation of benzoins to corresponding benzils. This reagent was easily prepared. The oxidation condition was mild and the products were easily separated with high yields. |
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| Keywords: | Trimethylammonium chlorochromate adsorbed on alumina Benzoins Oxidation Benzils. |
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