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新颖电化学气敏电极的研究
引用本文:吴志刚,周仲柏,查全性. 新颖电化学气敏电极的研究[J]. 应用化学, 1988, 0(5): 21-24
作者姓名:吴志刚  周仲柏  查全性
作者单位:武汉大学化学系电化学研究室
摘    要:
根据薄层电化学原理,首次提出并成功地研制了一类新颖的气体敏感电极——“气体薄层电报”;通过特殊测量系统的设计,借助简便的采样方式获得了快响应、高灵敏度和低温度系数的峰电流信号;进而比较系统地研究了这类电极的工作原理,基本上弄清了气体薄层电极的反应模式.

关 键 词:气敏电极  防水气体扩散电极  气体薄层电极  整体电解  
收稿时间:1987-07-27
修稿时间:1987-12-21

A NOVEL ELECTROCHEMICAL GAS-SENSITIVE ELECTRODE
Wu Zhigang Zhou Zhongbai Zha Quanxing. A NOVEL ELECTROCHEMICAL GAS-SENSITIVE ELECTRODE[J]. Chinese Journal of Applied Chemistry, 1988, 0(5): 21-24
Authors:Wu Zhigang Zhou Zhongbai Zha Quanxing
Affiliation:Department of Chemistry, Wukan University
Abstract:
A novel type of gassensitive electrode,a gas thin-layer electrode(GTLE),has been constructed by using hydrophobic gas diffusing electrode technique.Distinctive peaks appeared on linear sweep voltammetry curves as the result of exhaustive electrolysis of reactants within GTLE.The charge(Qp)correlated to the current peak was directly proportional to the amount of the reactant component in the pores of GTLE,thus its concentration in the gas sample can be detected. The measuring system is simple in construction,capable of fast sampling(<5S),with lower temperature coefficient(-0.1-0.3%/℃),high sensitivity and good stability.
Keywords:Gassensitive electrode  Hydrophobic gas diffusing electrode  Gas thin-layer eletrode  Bulk electrolysis  
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