| Hydroaminomethylation of 1-Dodecene Catalyzed by Water-soluble Rhodium Complex |
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| 引用本文： | YingYongWANG MeiMingLUO YaoZhongLI HuaCHEN XianJunLI. Hydroaminomethylation of 1-Dodecene Catalyzed by Water-soluble Rhodium Complex[J]. 中国化学快报, 2004, 15(7): 774-776 |
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| 作者姓名： | YingYongWANG MeiMingLUO YaoZhongLI HuaCHEN XianJunLI |
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| 作者单位： | [1]DepartmentofChemistrySichuanUniversity,Chengdu610064 [2]InstituteofHomogeneousCatalysisSichuanUniversity,Chengdu610064 |
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| 摘 要： | The hydroaminomethylation of 1-dodecene catalyzed by water soluble rhodium complex RhCI(CO)(TPPTS)2 in the presence ofsurfactant CTAB was investigated. High reactivity and selectivity for tertiary amine were achieved under relatively mild conditions.
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| 关 键 词： | 1-十二烯 水溶性铑配合物 双相催化系统 氢化氨甲基化作用 |
Hydroaminomethylation of 1-Dodecene Catalyzed by Water-soluble Rhodium Complex |
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| Ying Yong WANG,Mei Ming LUO,Yao Zhong LI,Hua CHEN,Xian Jun LI. Hydroaminomethylation of 1-Dodecene Catalyzed by Water-soluble Rhodium Complex[J]. Chinese Chemical Letters, 2004, 15(7): 774-776 |
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| Authors: | Ying Yong WANG Mei Ming LUO Yao Zhong LI Hua CHEN Xian Jun LI |
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| Affiliation: | Ying Yong WANG,Mei Ming LUO,Yao Zhong LI,Hua CHEN,Xian Jun LIDepartment of Chemistry,Institute of Homogeneous Catalysis Sichuan University,Chengdu 610064 |
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| Abstract: | The hydroaminomethylation of 1-dodecene catalyzed by water soluble rhodium complex RhCl(CO)(TPPTS)2 in the presence of surfactant CTAB was investigated. High reactivity and selectivity for tertiary amine were achieved under relatively mild conditions. |
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| Keywords: | Hydroaminomethylation 1-dodecene water-soluble rhodium complex biphasic catalytic system. |
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