Octahedral ruthenium (II) carbonyl complexes with nitrogen,sulphur and tin donor ligands |
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| Affiliation: | 4. National University of Science and Technology “MISIS”, Chemistry Department, 4 Leninskiy prospekt, 119049 Moscow, Russian Federation;1. Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland;2. Department of Inorganic Chemistry, University of Granada, Severo Ochoa s/n, 18071 Granada, Spain;3. Department of Parasitology, University of Granada, Severo Ochoa s/n, 18071 Granada, Spain;4. Faculty of Chemistry, Wrocław University, F. Joliot-Curie 14, 50-383 Wrocław, Poland;5. National Medicines Institute, Chełmska 30/34, 00-725 Warszawa, Poland;6. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warszawa, Poland |
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| Abstract: | The reaction of a carbonyl-containing ruthenium solution with amines leads to isolation of the amino-carbonyl complexes: [Ru(C6H5NH2)2(CO)2X2], [Ru(C6H5CH2NH2)2(CO)2X2], [Ru(phen)(CO)2X2] ( X = Cl, Br), [Ru(dipy)(CO)2Cl2] and [Ru{C6H4(S)NH2}(CO)2]. Preparation of the trihalostannato-carbonyl complexes [Ru(py)2(CO)2(SnX3)2] (X = Cl, Br), and [Ru(Et2S)3 (CO)2SnCl3]X (X = Cl, Ph4B) via the carbonyl-containing solution is also prepared. |
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