Oxidation of propene over various doped tungsten oxides |
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Authors: | S. De Rossi E. Iguchi M. Schiavello R. J. D. Tilley |
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Affiliation: | (1) Istitutio di Chimica Generale, and Centro di studio su Struttura ed attività catalitica di sistemi di ossidi del C.N.R., Università di Roma, Rome, Italy;(2) School of Materials Science, University of Bradford, BD71 DP Bradford, Yorkshire, England;(3) Present address: Department of Metallurgical Engineering, Yokohama National University, Ohka, Minami-Ku, 233 Yokohama, Japan;(4) Istituto di Chimica Generale ed Inorganica, Università di Roma, Rome, Italy |
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Abstract: | The oxidation of propene was studied on several tungsten oxides which contained small amounts of Ti, Ta, Nb and Sn. Only the Sn-containing specimen was found to be selective in the conversion of propene to acrolein. The catalytic results are correlated with crystal structures determined by electron microscopy.
, Ti, Ta, Nb Sn. , , Sn, . , . |
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