| Synthesis, Characterization, Spectroscopy and Study of Antimicrobial Properties of Two New Substituted Trichloroaluminate（Ⅲ） Complexes [AlCl3X]- （X = SCN-, CN-） |
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| 作者姓名： | Zahra Shokri Aghbolagh Shahriar Ghammamy Sajjad Sedaghat Shahram Jahandide |
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| 作者单位： | Young Research Club, Takestan Branch Islamic Azad University, Takestan, Iran;Department of Chemistry, Faculty of Science, Islamic Azad University, Malard Branch, Malard, Iran;Department of Chemistry, Faculty of Science, Islamic Azad University, Ardabil Branch, Ardabil, Iran |
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| 基金项目： | the research Office of Azad Islamic University,Ardebil,for supporting this work |
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| 摘 要： | The synthesis and characterization of two new aluminate(Ⅲ) complexes with general formula K[AlCl3X] are reported. These compounds derived from aluminate trichloride and related salts. Potassium trichlorothiocyanoaluminate, PCTA, and potassium trichlorocyanatoalu-minate, PCCA, are two new ionic aluminate complexes. They can be easily synthesized in a nearly quantitative yield by using the direct reaction of AlCl3 and KX. The complexes were characterized by physico-chemical and spectroscopic methods. Theoretical calculations have been used for the extraction of structural and spectroscopic data of these new synthesized complexes. The antibacterial activities of such compounds were studied against the Staphylococcus aureus, Escherichia coli, Staphylococcus Epidermidis, Estreptococo B and Shigella.
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| 关 键 词： | aluminate compounds synthesis characterization PCTA PCCA theoretical calculation antibacterial activities |
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