Isomerization of 3-aryl-4-sulfolenes and their reaction with some nucleophilic reagents |
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| Authors: | T. É. Bezmenova S. M. Lukashov V. P. Tantsyura T. S. Lutsii A. F. Rekasheva T. D. Zaika |
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| Affiliation: | (1) Institute of the Chemistry of Macromolecular-Weight Compounds, Academy of Sciences of the Ukrainian SSR, Kiev |
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| Abstract: | ![]()
Bases convert 3-(4-substituted phenyl)-4-sulfolenes to 3-aryl-3-sulfolenes, which are subsequently isomerized to 3-aryl-2-sulfolenes. The ratios of the products depend on the character of the substituent in the phenyl ring, and electron-acceptor substituents accelerate the isomerization.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1072–1077, August, 1975. |
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