Isomerization of 3-aryl-4-sulfolenes and their reaction with some nucleophilic reagents |
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Authors: | T É Bezmenova S M Lukashov V P Tantsyura T S Lutsii A F Rekasheva T D Zaika |
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Institution: | (1) Institute of the Chemistry of Macromolecular-Weight Compounds, Academy of Sciences of the Ukrainian SSR, Kiev |
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Abstract: | Bases convert 3-(4-substituted phenyl)-4-sulfolenes to 3-aryl-3-sulfolenes, which are subsequently isomerized to 3-aryl-2-sulfolenes. The ratios of the products depend on the character of the substituent in the phenyl ring, and electron-acceptor substituents accelerate the isomerization.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1072–1077, August, 1975. |
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