The electrochemical oxidation of polyfluoroaromatic amines—II The synthesis of substituted polyfluorophenazines |
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| Authors: | A G Hudson M L Jenkins A E Pedler and J C Tatlow |
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| Institution: | Department of Chemistry, University of Birmingham, Birmingham, 15 UK |
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| Abstract: | 1- and 2-Methoxy-heptafluorophenazine and 1- and 2-bromoheptafluorophenazine have been obtained by anodic oxidation of appropriately substituted 2-amino-octafluorodiphenylamines, the synthesis of which is described. By reaction of octofluorophenazine with suitable nucleophiles, 2-methoxy-, 2-hydroxy and 2-N,N1-dimethylamino-heptafluorophenazine were formed; some of their reactions are described. |
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