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Conversion of N-acetylneuraminic acid glycosyl chloride into dibenzyl glycosyl phosphate: O-glycosylation in the absence of a promoter |
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| Authors: | A. M. Shpirt L. O. Kononov V. I. Torgov V. N. Shibaev |
| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
| Abstract: | Readily accessible N-acetylneuraminic acid (Neu5Ac) glycosyl chloride, which was regarded to be a poor glycosyl donor, was shown to react with dibenzyl phosphoric acid salts in the absence of glycosylation promoters to give the corresponding  -Neu5Ac dibenzyl glycosyl phosphate in high yield. |
| Keywords: | sialic acids N-acetylneuraminic acid glycosyl chloride glycosyl phosphates monosaccharides NMR spectroscopy |
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