Synthesis and Characterization of 2d Ferromagnetic (RNH3)2CrX4 Containing Mixed-Halides,R = CnH2n+1, X = Br,C1 |
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| Authors: | Carlo Bellitto |
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| Affiliation: | Istituto di Teoria e Struttura Elettronica dei Composti di Coordinazione del C.N.R. , Area della Ricerca di Roma, Via Salaria Km. 29.5, C.P.10, 00016, Monterotondo Staz., (Roma), Italy |
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| Abstract: | ![]()
The bis(benzylammonium)tetrahalogenochromate(II), (C6H5CH2NH3)2CrBr3. 3Cl0. 7, has been synthesized and characterized. The crystal structure is related to that of K2NiF4. The compound is ferromagnetic and the Curie temperature TC (TC= 49 K) has been measured by a mutual inductance technique. The susceptibility increases sharply at TC and then shows a drop-off below TC, typical of a single-domain powder sample. The compound is found to behave as a typical 2D easy plane ferromagnet. |
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| Keywords: | Phase behavior miscibility Flory-Huggins interaction parameter crosslinked polymer network nematic liquid crystals |
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