Onsager model for a variable dielectric permittivity near an interface |
| |
Authors: | REIMAR FINKEN VINCENT BALLENEGGER JEAN-PIERRE HANSEN |
| |
Affiliation: | Department of Chemistry , University of Cambridge , Cambridge , CB2 1EW , UK |
| |
Abstract: | ![]() Using a generalization of an Onsager type approach, we are able to predict a dielectric permittivity profile of an inhomogeneous dipolar fluid in the presence of a dielectric interface. The reaction and cavity fields are calculated semi-analytically using bispherical coordinates. An asymptotic expression for the local permittivity is derived as a function of distance from the interface. |
| |
Keywords: | |
|
|