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Onsager model for a variable dielectric permittivity near an interface
Authors:REIMAR FINKEN  VINCENT BALLENEGGER  JEAN-PIERRE HANSEN
Institution:Department of Chemistry , University of Cambridge , Cambridge , CB2 1EW , UK
Abstract:Using a generalization of an Onsager type approach, we are able to predict a dielectric permittivity profile of an inhomogeneous dipolar fluid in the presence of a dielectric interface. The reaction and cavity fields are calculated semi-analytically using bispherical coordinates. An asymptotic expression for the local permittivity is derived as a function of distance from the interface.
Keywords:
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