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Ring-closing metathesis in aqueous micellar medium
Authors:Laville Lionel  Charnay Clarence  Lamaty Frédéric  Martinez Jean  Colacino Evelina
Affiliation:Institut des Biomolécules Max Mousseron, UMR 5247 CNRS-UM I-UM II, Université Montpellier II, Place E. Bataillon, 34095 Montpellier Cedex 5, France.
Abstract:
Underwater exploration: The ring-closing metathesis of N,N-diallyltosylamine (DATs) and diallyldiethyl malonate has been studied in aqueous micellar medium, at room temperature, in the presence of four different gemini cationic surfactants and various ruthenium catalysts. For the first time, the adsorption mechanisms and the reaction steps involved in this heterogeneous catalytic process were elucidated.
Keywords:heterogeneous catalysis  micelles  reactions in water  ring‐closing metathesis  ruthenium  surfactants
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