| 螺噁嗪光致变色反应机理研究进展 |
| |
| 引用本文： | 冯长根,王建营. 螺噁嗪光致变色反应机理研究进展[J]. 有机化学, 2006, 26(7): 1012-1023 |
| |
| 作者姓名： | 冯长根 王建营 |
| |
| 作者单位： | 北京理工大学爆炸科学与技术国家重点实验室，北京理工大学爆炸科学与技术国家重点实验室，解放军总装备部防疫防护大队北京100101 北京100081，北京100081 |
| |
| 摘 要： | 20世纪80年代中期以来, 关于螺噁嗪在光致变色过程中的光化学和光物理现象的研究非常活跃. 综述了近20年来对溶液中的螺噁嗪、晶体螺噁嗪以及固体介质中的螺噁嗪的光致变色机理研究结果, 同时介绍了实验研究方法和理论研究方法在螺噁嗪光致变色过程研究中的应用, 分析了取代基对光致变色性质的影响. 阐述了机理研究对新型螺噁嗪设计合成的重要指导意义.
|
| 关 键 词： | 螺噁嗪 光致变色机理 动力学 取代基效应 |
| 收稿时间： | 2005-08-04 |
| 修稿时间： | 2006-01-25 |
Progress in the Photochromic Mechanism of Spirooxazine |
| |
| FENG Chang-Gen,WANG Jian-Ying. Progress in the Photochromic Mechanism of Spirooxazine[J]. Chinese Journal of Organic Chemistry, 2006, 26(7): 1012-1023 |
| |
| Authors: | FENG Chang-Gen WANG Jian-Ying |
| |
| Affiliation: | (State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technol-ogy, Beijing 100081)( Military Unit of Epidemic Prevention and Protection, Head-quarters of General Equipment, The People’s Liberation Army of China, Beijing 100101) |
| |
| Abstract: | The study on photochemistry and photophysics of spirooxazines in the photochromic reactions has been the focus since the middle of 1980s. The photochromic mechanism of spirooxazines, which was studied in different medium the past 20 years, such as solution, crystal or solid, was reviewed. The new ex- perimental methods, technologies and theory applied to study the photochromic process of spirooxazines were mainly introduced, and the substitution effects on the photochromic properties were analyzed. The typical examples were used to explain the important steering meaning on the study of design, synthesis and applications. |
| |
| Keywords: | spirooxazine photochromic mechanism kinetics substitution effect |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
|
点击此处可从《有机化学》下载全文 |
