New reactions in water: metal-free conversion of alcohols and ketones into alpha-iodoketones |
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| Authors: | Barluenga José Marco-Arias María González-Bobes Francisco Ballesteros Alfredo González José M |
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| Affiliation: | Instituto de Química Organometálica Enrique Moles, Universidad de Oviedo, Oviedo, 33006, Spain. barluenga@uniovi.es |
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| Abstract: | ![]()
Using water as the reaction medium, ketones can be transformed into alpha-iodoketones upon treatment with sodium iodide, hydrogen peroxide and an acid; interestingly, alpha-iodoketones can be also obtained from secondary alcohols through a metal-free tandem oxidation-iodination approach. |
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