Oxidation of alcohols using a manganese (II) complex based on a pentakis benzimidazole amide ligand |
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| Authors: | Manisha Singla Pavan Mathur |
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| Affiliation: | aDepartment of Chemistry, Delhi University, Delhi 110007, India |
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| Abstract: | A pentakis benzimidazole based penta-amide ligand diethylenetriamine—N,N,N′,N′,N″-pentakis(2-methyl benzimidazolyl)penta-amide [GBDTPA] has been synthesized and utilized to prepare Mn (II) complexes of general composition [Mn2(GBDTPA)X4], where X is an exogenous anionic ligand (X = Cl−, NO3− and Br−). The oxidation of alcohols has been investigated using [Mn2(GBDTPA)Cl4] as the catalyst and TBHP as an alternate source of oxygen. The respective aldehydic products have been isolated and characterized by 1H NMR. |
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| Keywords: | Manganese (II) EPR Catalysis Benzimidazole amides |
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