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| STRUCTURE OF [Et4N]2[Mo2（CO）8（SCH2C6H4CH2SH）] | |
| 引用本文： | 黄梁仁,庄伯涛,等. STRUCTURE OF [Et4N]2[Mo2（CO）8（SCH2C6H4CH2SH）][J]. 结构化学, 1989, 8(1): 19-22 |
| 作者姓名： | 黄梁仁 庄伯涛 等 |
| 摘 要： | <正> Mr =1015.05, P21/c, a= 10.912(4), b= 12.088(3), c= 18.807(8) A.β=103.57(3)° ,V= 2411.4 A3, Z = 2, DC = 1.40 g/cm3.λ(MoKα)= 0.71073 A, μ=7.2 cm-1,F(000)=1048.Room temperature, final R=0.069, Rw=0.091. The geometry around the Mo atom is a distorted octahedron. The equatorial Mo-C distances are shorter than the axial ones. The Mo...Mo distance is 3.949A. |
| 关 键 词： | 四乙基铵 羰基 二元配合物 钼 晶体结构 邻苯二甲硫醇 |
STRUCTURE OF [Et_4N]_2[Mo_2(CO)_8(SCH_2C_6H_4CH_2SH)] |
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| Abstract: | Mr =1015.05, P21/c, a= 10.912(4), b= 12.088(3), c= 18.807(8) A.β=103.57(3)° ,V= 2411.4 A3, Z = 2, DC = 1.40 g/cm3.λ(MoKα)= 0.71073 A, μ=7.2 cm-1,F(000)=1048.Room temperature, final R=0.069, Rw=0.091. The geometry around the Mo atom is a distorted octahedron. The equatorial Mo-C distances are shorter than the axial ones. The Mo...Mo distance is 3.949A. |
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