Synthesis and coordination properties of new bis(phosphinomethyl)pyridine N,P,P'-trioxides |
| |
Authors: | Gan X M Duesler E N Paine R T |
| |
Institution: | Department of Chemistry, University of New Mexico, Albuquerque, New Mexico 87131, USA. |
| |
Abstract: | In a search for more hydrocarbon solvent soluble derivatives of the parent ligand, 2,6-Ph(2)P(O)CH(2)](2)C(5)H(3)NO (1a), a series of new ligands, 2,6-R(2)P(O)CH(2)](2)C(5)H(3)NO R = Bz (1b); Tol (1c); Et (1d); Pr (1e); Bu (1f); Pn (1g); Hx (1h); Hp (1i); and Oct (1j)] and 2,6-RR'P(O)CH(2)](2)C(5)H(3)NO R = Ph, R' = Bz (2a); R = Ph, R' = Me (2b); R = Ph, R' = Hx (2c); R = Ph, R' = Oct (2d)], have been prepared by either Arbusov or Grignard substitutions on 2,6-bis(chloromethyl)pyridine followed by N-oxidation. The new ligands have been characterized by spectroscopic methods, and their coordination chemistry with selected lanthanide ions has been surveyed. Several 1:1 and 2:1 ligand/metal complexes have been isolated, and single-crystal X-ray diffraction analyses for Nd(2a)(NO(3))(3), Er(2a)(NO(3))(3), Yb(1d)(NO(3))(3), and Nd(1c)(2)](NO(3))(3) are described. The new structural data are discussed in relation to the structures of complexes formed by 1a. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|