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The insertion of the dioxides of carbon and sulphur into the palladium-carbon bond
Authors:Trinh Hung  PW Jolly  G Wilke
Institution:Max-Planck-Institut für Kohlenforschung, Lembkestr. 5, D-4330 Mülheim a.d. Ruhr, W.-Germany
Abstract:Bis ( η1, η2-allyl) palladium phosphine complexes react with carbon dioxide and sulphur dioxide by insertion into the palladium-carbon σ-bond to give η3-allylpalladium-carboxylate and -S-sulphinate complexes.
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