Reactions of <Emphasis Type="Italic">N,N</Emphasis>-dihexyloctanamide with nitrate and dodecane radicals: a pulse radiolysis study |
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| Authors: | Ravi Joshi P N Pathak V K Manchanda S K Sarkar T Mukherjee |
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| Institution: | (1) Radiation & Photochemistry Division, Bhabha Atomic Research Center, Trombay, Mumbai, 400 085, India;(2) Radiochemistry Division, Bhabha Atomic Research Center, Trombay, Mumbai, 400 085, India;(3) Chemistry Group, Bhabha Atomic Research Center, Trombay, Mumbai, 400 085, India |
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| Abstract: | Recently, completely incinerable N,N-dihexyloctanamide (DHOA) has been identified as a promising alternative to tri-n-butyl phosphate for the reprocessing of spent nuclear fuels. The present work deals with the pulsed radiolytic investigation
on the reactions of DHOA with the radicals produced in the radiolysis of nitric acid and dodecane medium. The rate constants
of the reactions of DHOA with solvated electron, nitrate radical and dodecane radicals have been measured and the transients
have been characterized. In addition, the reactions of DHOA transients have also been studied. |
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