Induction period of the conversion of methanol to hydrocarbons on a nickel loaded faujasite: Evidence for a suppression of the autocatalytic step |
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Authors: | N Jaeger A Jahn and G Schulz-Ekloff |
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Institution: | (1) Research Group Applied Catalysis Department of Chemistry, University of Bremen, D-2800 Bremen, FRG |
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Abstract: | The conversion of methanol to hydrocarbons on nickel loaded faujasites can be retarded for many hours time-on-stream. The induction period is interpreted to be due to a suppression of the autocatalytic step of the reaction. An autocatalytic mechanism is proposed based on the -scission of branched carbenium ion intermediates.
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