Electronic processes andZ centres in NaCl and KC1 crystals

The paper gives the experimental results of the team-work study of coloured pure and Ca doped NaCl and KC1 crystals. The mechanism of the formation ofR centres by coagulation ofF centres and of the formation ofZ centres fromF centres, cation vacancies and Ca ions is discussed. An alternative model forZ ₃ centres is proposed. The possible connections between physical and chemical behaviour are indicated.

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Z- NaCl 1

NaCl KCl . R- F- Z- F-, Ca. Z ₃-. .

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This work was presented by the courtesy of Prof. R. Maurer at the Symposium on Color Centers, Corvallis, Oregon (1959).

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The authors wish to express their gratitude to K. Suk, K. Listoová and M. Javrková for carefully carrying out the measurements and I. Kunzlová and L. Nováková for preparing the crystals.