Dihedral angle study in Hesperidin using NMR Spectroscopy |
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| Authors: | Yashwantsinh S Jadeja Khushal M Kapadiya Hetal J Jebaliya Anamik K Shah Ranjan C Khunt |
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| Institution: | Centre of Excellence, NFDD Complex, Department of Chemistry, Saurashtra University, Rajkot, Gujarat, India |
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| Abstract: | Hesperidin is flavonoid molecule found in citrus fruits (Citrus reticulata), especially difficult to extract, classify and characterize. Present work is to study the unresolved relative configuration of Hesperidin through the dihedral angle, coupling constant and different NMR techniques. The Karplus equation and its modifications have been originated from the valence bond theory and associated with dihedral angle and coupling constant. The result data set of calculated dihedral angle can probe significant method to assign the virtual configuration of natural products and also resolved stereochemistry of Hesperidin at C‐2 position in. Copyright © 2016 John Wiley & Sons, Ltd. |
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| Keywords: | 1H NMR 13C NMR 2D NMR Dihedral angle Coupling constant MestReJ v1 1 Hesperidin |
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