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Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N |
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| Authors: | Lartigue Lenaïc Pflieger Rachel Nikitenko Sergey I Guari Yannick Stievano Lorenzo Sougrati Moulay T Larionova Joulia |
| Institution: | Institut Charles Gerhardt Montpellier, UMR 5253, Chimie Moléculaire et Organisation du Solide, Université Montpellier II, Place E. Bataillon, F-34095, Montpellier Cx5, France. |
| Abstract: | The autocatalytic sonochemical reaction of Fe(CO)(5) decomposition in BuMeIm]Tf(2)N] provides iron nanoparticles in higher yields than in tetralin. Such a difference is explained by the higher decomposition of the intermediate Fe(3)(CO)(12) according to the two-sites model of the sonochemical reactions and the specific properties of the ionic liquid. |
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