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Phosphine oxide-functionalized polyfluorene derivatives:Synthesis,photophysics,electrochemical properties,and electroluminescence performance
Affiliation:GUO ZengShan1,LIU DeAng3,WANG Cheng1,PEI Jian1,ZHOU ZhangLin2,ZHAO LiHua2,GIBSON Gary2,BRUG James2,LAM Sity2 & MAO Samuel S.3 1Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China 2Information Surfaces Lab,Hewlett Packard Labs,Hewlett Packard Company,1501 Page Mill Road,Palo Alto,CA 94304,USA 3Lawrence Berkeley National Laboratory and Department of Mechanical Engineering,University of C...
Abstract:A series of phosphine oxide-functionalized polyfluorene derivatives,PFH-PO-40-1 (P1),PFH-PO-20-1 (P2),PFH-PO-10-1 (P3),and PFH-PO-1-1 (P4),were prepared via a palladium-mediated Suzuki cross-coupling reaction.The structures and purities of all polymers were fully characterized by 1H and 13C NMR,UV-vis and photoluminescent spectroscopy,gel permeation chromatography,and TGA/DSC.Their emission features showed single broad peaks at about 445 nm in film,compared with those in dilute solutions,which might be caus...
Keywords:organic light-emitting diodes  polyfluorene derivatives  electroluminescence  
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