Chlorodimethyl(N‐methylpyrrolidinone)tin(IV)‐μ‐chloro‐dichlorodimethyltin(IV) |
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Authors: | Uwe‐Christoph Knig Michael Berkei Claudia Hirsch Hans Preut Terence Nigel Mitchell |
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Institution: | Uwe‐Christoph König,Michael Berkei,Claudia Hirsch,Hans Preut,Terence Nigel Mitchell |
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Abstract: | The synthesis and the X‐ray structural analysis of the title compound, μ‐chloro‐1:2κ2Cl‐trichloro‐1κCl,2κ2Cl‐tetramethyl‐1κ2C,2κ2C‐(N‐methylpyrrolidin‐2‐one)‐1κO‐ditin(IV), Sn2Cl4(CH3)4(C5H9NO)], are described. The title compound is found to exhibit a distorted trigonal–bipyramidal geometry at both SnIV atoms. The Sn—Cl—Sn angle involving the bridging chlorine ligand is 135.56 (5)°, with the Sn—Cl bond lengths being 2.5704 (13) and 3.1159 (13) Å. |
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